What is Osmosis?
How Osmosis Affects GRP Hulls.
Osmosis is the condition of visible blisters on a boat's hull, caused by water absorption.
The process of osmosis is the same mechanism by which plants and trees draw water up from the soil to their branches and leaves.
Main Causes of Osmosis.
Long periods afloat without lay-ups. Warm tropical waters. Fresh water is worse than salt water. Resins that are colored (including white ones) are more affected than clear resins.
The Process of Osmosis.
The fibreglass moldings on a yacht hull are not completely waterproof. Individual water molecules are so small that they can find their way into the layers of glass and resin which form the boat's hull. When molecules of water mix with chemicals inside the laminate, problems start to happen. These are chemicals such as water-soluble materials, emulsion binders for example. The water molecules can then have a chemical reaction with these substances, forming larger molecules of a new chemical, often acidic. Unlike the original small water molecules, these cannot pass through fibreglass and become trapped. This is the point at which osmosis starts.
Waterproof Fiberglass Moldings.
A fibreglass, or glass reinforced plastic (GRP), molding is made up of thin glass strands. On their own the glass strands are strong but flexible. When fused with resin it results in a more durable substance. Ideally the final molding should have lots of glass and only enough resin to hold it together and seal in the glass strands, but most conventional moldings have much more resin than this. Generally, the outside of a fibreglass hull is coated in a resin called a gelcoat. This forms the hard outer surface of the hull. Most yacht builders mold the hulls layer by layer, allowing each layer to set before putting on the next.
The one exception to this process is vacuum bagging or resin infusion molding. This is where dry layers of glass cloth and mat are laid in a mold, and held in place by either an inflated plastic balloon, or another close-matching mold. The resin is then drawn into the fibers by vacuum suction.
The process is more expensive, but is capable of producing very light, strong laminates with a high glass content, and most importantly, very few air bubbles.
Types of Resin.
The earliest resins were orthopthalic polyester resins, used in the 1960s. By around 1980, isopthalic polyester resins started to be used as well by some builders, as they were more water resistant. Most builders used these more expensive isopthalic resins only for the first outer coats, and then saved money by using the cheaper orthopthalic resins for the inner layers.
Some builders have also used double layers of gelcoat, in an attempt to stop osmosis occurring.
Vinylester is the newest resin on the market and as such is the most costly, but it is even more waterproof than isopthalic polyester.
Treatments for Osmosis.
1) The best option in most cases is to cut or grind open individual blisters, repeatedly wash out with hot water or steam, to remove the 'blister juice' from any blisters, dry thoroughly and fill with epoxy paste.
2) On older boats, if there are no blisters, and even if a moisture meter shows high readings, one option is to do nothing! If there are blisters but they are small, they are not likely to have any significant effect on the structural strength.
3) Go to your local 'Osmosis Treatment Centre' and have the gelcoat removed, the hull washed and dried out, and the hull recoated with epoxy. This is a costly process and therefore should only be used if all else fails.
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Source: http://ezinearticles.com/
Added: March 27, 2008
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